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cohesive and adhesive forces ppt

Cohesive forces are attractive forces between similar molecules. is the property of its rightful owner. Hence water droplets are spherical. the adhesive forces are greater than the cohesive ones and the cohesive forces aren't big enough to overcome the pull of gravity. 3. These forces vary inversely as the eighth power of distance between the molecules. Such forces cause liquid drops to cling to window panes, for example. States of Matter I The gaseous state: (i) Ideal gas behaviour and deviations from it (II) pV = nRT and its use in determining a value for Mr II The liquid state The kinetic concept of the liquid state and simple kinetic-molecular descriptions of, - I The gaseous state: (i) Ideal gas behaviour and deviations from it (II) pV = nRT and its use in determining a value for Mr II The liquid state, - Title: Ch 11: Intermolecular Forces Last modified by: FCS Created Date: 11/28/2004 2:18:48 PM Document presentation format: On-screen Show Other titles. The figure below illustrates adhesion and cohesion forces present within an adhesive and between an adhesive and substrate. Mercury, for example, has a very large surface tension and a large contact angle with glass. Key Words: cohesion, adhesion, meniscus, wetting, intermolecular forces ----- cation + learning's teaching materials and assessments are thoughtful and focused. The later approach also. 2. Liquids can, for example, be held in open containers because cohesive forces hold the molecules together. It's FREE! The particle adhesion forces of silica particles on Cu wafers in three different cleaning solutions were compared with those in DI H 2 O [40].The lowest adhesion force was observed to be 0.0124 nN in citric acid (C 2 H 6 O 4) with NH 4 OH at pH = 6. Or use it to upload your own PowerPoint slides so you can share them with your teachers, class, students, bosses, employees, customers, potential investors or the world. Carry Handle Adhesive Tapes Market Forecast, Trends Analysis Report 2018-2025. See our Privacy Policy and User Agreement for details. Adhesive forces are attractive forces between molecules of different materials. Practice: Cohesion, adhesion, and surface tension. Everything you can see, touch, smell or taste in your room is made of matter. Attractive forces between molecules of the same type are called cohesive forces. Water. In other words, the cohesive strength of the adhesive, and not the adhesion bet-ween adhesive and the substrate, may be the limiting factor in bond strength tests and in clinical practice. Structure of Matter Author: Mahmoud Last modified by: f5, Intermolecular Forces and Some Properties of Liquids. Cohesive and adhesive forces are associated with bulk (or macroscopic) properties, and hence the terms are not applicable to the discussion of atomic and molecular properties. The force of adhesion is defined as the force of attraction between different substances, such as glass and water. Also, it highlights the in-depth market analysis with the latest trends, drivers and its segments with respect to regional and country. The ring is formed by the alcohol/water mixture climbing the walls Clipping is a handy way to collect important slides you want to go back to later. Attractive forces between molecules of different types are called adhesive forces. 4. Table 2 lists contact angles for several combinations of … Cohesive Forces ... Supercritical Fluids. Liquids can, for example, be kept in open containers because cohesive forces hold the molecules together. Liquids can, for example, be held in open containers because cohesive forces hold the molecules together. Gases are floating around you and in bubbles. The smaller θ is, the smaller the relative strength, so that the adhesive force is able to flatten the drop. 3.ForcesinAdhesion In order for this activity to work, the needle needs to be very clean as even the oil from your fingers can be sufficient to affect the Attractive forces between molecules of the same type are called cohesive forces. We use your LinkedIn profile and activity data to personalize ads and to show you more relevant ads. fractures due to cohesive failure of the adhesive rather than failure of the adhesive-substrate bond. Formation of bond at interface Cohesion same kind of molecules involved Bonding of similar materials at their interface Like joining two metal pieces together by welding Adhesive & cohesive forces Adhesion and cohesion co-exist ADHESION 6. Cohesive forces and adhesive forces are van der Waals’ forces. Many of them are also animated. Hydrogen Bonding •Attraction between hydrogen atoms who are bonded to strongly electronegative atoms like O, F, or Cl and another polar molecule. a) stronger, higher. But the surface molecules do not have molecules on all sides. (1) Try floating a sewing needle on water. The force of cohesion is defined as the force of attraction between molecules of the same substance. And Planning, Greater Noida. Cohesive and adhesive forces are important for the transport of water from the roots to the leaves in plants. Specifically, these attractive forces … G.Bregliozzi - VSC-LBV Section. Surface attachment process between two dissimilar substances is called adhesion. It's made of sugar and water: a classic adhesive recipe used since - Chapter 2, Section 1 Four States of Matter Matter is made of atoms and molecules that are always in motion The state of matter is determined by how fast the particles ... Purpose/ Relevance: Determine the adhesion forces between explosive articles and various substrates of interest at different conditions. See our User Agreement and Privacy Policy. Attractive forces between molecules of the same type are called cohesive forces. 2018 Hot Melt Adhesives Market - Industry Research Report, Market Share, Size, Geography & Revenue Assessment to 2024 (1). Customer Code: Creating a Company Customers Love, Be A Great Product Leader (Amplify, Oct 2019), Trillion Dollar Coach Book (Bill Campbell). What determines the state of matter a molecule is at room temperature? - The global Hot Melt Adhesives Market is estimated and forecasted in terms of revenue (USD million) and volume (KT) generated by the global market. For eg. Do you have PowerPoint slides to share? These forces create a “pull” on the water column. - What is matter? Shop online 3M Double-Coated Tapes. Phases of Matter and Intermolecular Forces, - Title: Kinetic Molecular Theory, Intermolecular Forces, Liquids and Solids Author: Lake Travis ISD Last modified by: Lake Travis ISD Created Date. Water molecules bead together on a wax paper bec… - Changing States of Matter The second state of matter we will discuss is a liquid. Attractive forces between molecules of different types are called adhesive forces. Mass is the amount of matter in a substance or object. Water-Water; Mercury-Mercury; 1. - Particle adhesion to substrates and their efficient collection Yehuda Zeiri (PI) Paz Elia (student), Ben-Gurion University, Israel Purpose/ Relevance: Determine the ... - Properties of Matter Physical properties Matter can have many different properties The properties determine how matter looks, feels, and is effected by energy & forces. The Adhesive Zone. Such forces cause liquid drops to cling to window panes, for example. PowerPoint presentation | free to download - id: 40395f-YTg3N. PPT – 1. Such forces cause liquid drops to cling to window panes, for example. Looks like you’ve clipped this slide to already. London Dispersion Forces ... - 1.2 Investigating Matter Matter is anything that has mass and volume. CrystalGraphics 3D Character Slides for PowerPoint, - CrystalGraphics 3D Character Slides for PowerPoint. This pull results from the tendency of water molecules being evaporated on the surface of the plant to stay connected to water molecules below them, and so they are pulled along. Use the principles of cohesive and adhesive forces to explain this situation. Surface tension is the result of cohesive forces between adjacent molecules. SUBMITTED BY Adhesive forces cause dissimilar surfaces to get attracted to each other. The adhesion and cohesion forces, both vary in their strengths. A high boiling azeotrope has adhesive forces that are _____ than cohesive forces, such that it boils at a _____ temperature than the boiling temperatures of the pure substances making up the mixture. If so, share your PPT presentation slides online with PowerShow.com. Liquids can, for example, be kept in open containers because cohesive forces hold the molecules together. Adhesive forces can be mechanical forces that cause molecules to stick together or can be electrostatic forces that exist between positive and negative charges. - Intermolecular Forces and Some Properties of Liquids. To overcome these limitations, we have developed a novel peel force technique to quantify both the adhesive and cohesive strengths of airway mucus. Cohesive forces exist between similar surfaces. This worksheet begins with defining adhesion, wetting and cohesion. And, best of all, most of its cool features are free and easy to use. FAHEEM AHMED Coupling room temperature beam vacuum system with collimators: Gained experience, - Coupling room temperature beam vacuum system with collimators:Gained experience & Outlook. When a liquid comes into contact with a surface (such as the walls of a graduated cylinder or a tabletop), both cohesive and adhesive forces will act on it. Mass is often measured in grams or kilograms. Attractive forces between molecules of the same type are called cohesive forces. Solids are hard things you can hold. The cohesive strength of a luting agent or adhesive, regardless of its chemical composition, is determined by a number of molecular forces: (1) the chemical bonds within the adhesive material, (2) chemical bonds due to crosslinking of the polymer (s) within a resin-based material, (3) intermolecular interactions between the adhesive molecules, and (4) mechanical bonds and interactions between the … SUBMITTED BY AKANKSHA SHARMA ANEES KHAN FAHEEM AHMED Apeejay School Of Architecture And Planning, Greater Noida 2. PowerShow.com is a leading presentation/slideshow sharing website. c) weaker, higher. What is Adhesive, Types Of Adhesive, Adhesive Properties, Market Survey, Market Price, Available Adhesive, Advantage Of Adhesive, Disadvantage. Jam sandwiches may not be the first thing to spring to your mind when you think about adhesives, but the jam is working as a kind of glue. A ADHESIVE IS A SUBSTANCE WHICH IS USE TO JOIN TWO OR MORE PARTS SO AS TO FORM A SINGLE UNIT . The forces which are Cohesive between molecules that cause the surface of a liquid to contract that too to the smallest possible surface area. Ppt on Adhesives 1. Hence they are pulled inwards causing the liquid to shrink to form a surface with minimum area, a sphere. The forces which are attractive between molecules of different types are known as adhesive forces. The larger the strength of the cohesive force relative to the adhesive force, the larger θ is, and the more the liquid tends to form a droplet. Whether your application is business, how-to, education, medicine, school, church, sales, marketing, online training or just for fun, PowerShow.com is a great resource. 1. This market research report presents a comprehensive analysis of key market forces boosting and restraining market growth. Attractive forces between molecules of different types are called adhesive forces. Formula for Calculation of Surface Tension: Cohesion holds hydrogen bonds together to create surface tension on water. Boasting an impressive range of designs, they will support your presentations with inspiring background photos or videos that support your themes, set the right mood, enhance your credibility and inspire your audiences. - States of Matter States of Matter Heating Curve Factors Affecting State Vapor Pressure IMF There are 3 types of IMF of different strengths. If you continue browsing the site, you agree to the use of cookies on this website. Effects of Cohesive and Adhesive Forces. Slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. Attractive forces between molecules of different types are called adhesive forces. Such forces cause liquid drops to cling to window panes, for example. And they’re ready for you to use in your PowerPoint presentations the moment you need them. presentations for free. As mentioned above, the adhesive has a modified molecular structure in the adhesion zone due to bonding to the substrate surface. That's all free as well! Attractive forces between molecules of different types are called adhesive forces. cohesive force is a force that acts between the molecules of a similar object and adhesive force is the force acting between the molecules of two different objects. Matter is anything that occupies space and has a mass. A strong adhesive force tends the liquid to spread over the surface whereas a strong cohesive force is responsible for the formation of water droplets on the water surface. The actual effect depends on the relative strength of the cohesive and adhesive forces and, thus, the contact angle given in the table. When liquid is placed on a smooth surface, the relative strengths of the cohesive and adhesive forces acting on that liquid determine the shape it will take (and whether or not it will wet the surface). d) weaker, lower The molecules in the bulk of a liquid are pulled equally in all directions by the neighboring molecules. Attractive forces between molecules of the same type are called cohesive forces. - 1.2 Matter and Its Properties ... volume indefinite shape atoms move very quickly atoms are far apart pretty weak attractive forces Changes of State Plasma high ... - Ch. If you continue browsing the site, you agree to the use of cookies on this website. Attractive forces between molecules of different types are called adhesive forces. Liquids can, for example, be held in open containers because cohesive forces hold the molecules together. Attractive forces between molecules of the same type are called cohesive forces. - The new Carry Handle Adhesive Tapes Market report offers a comprehensive study of the present scenario of the market coupled with major market dynamic. The measurements carried out utilizing both AFM measurement and aerodynamic jet experiments. Van der Waals Forces •The sum of all attractive forces between molecules. Critical Temperatures and Pressures. 1: Matter and Change 1.2 Matter and Its Properties Terms Matter- anything that has mass and volume Atom- smallest unit of an element that keeps the properties of ... - Chapter 11,12 Matter, Fluid Mechanics Totally Submerged Object, 2 The object is more dense than the fluid The net force is downward The object accelerates downward ... - chapter - 1 matter in our surroundings class :- ix made by :- manas mahajan school :- k.v ... - Polyurethane Adhesives offer versatile curing times at room and elevated temperatures. 4 examples are then discussed. What determines the ability of a molecule to develop cohesive and adhesive forces?" The attractive forces which are between molecules of the same type are known as the cohesive forces. Define surface tension. Liquids can, for example, be kept in open containers because cohesive forces hold the molecules together. ANEES KHAN The term "cohesive forces" is a generic term for the collective intermolecular forces (e.g., hydrogen bonding and van der Waals forces) responsible for the bulk property of liquids resisting separation. Ex- between water-water molecules. This chemistry video tutorial focuses on the cohesive and adhesive forces that are found in water. - Tgoldkamp is a popular industrial product distributor network source in USA, supplies a wide range of high-performance Double coated tapes such as tissue tape, adhesive transfer tape, paper tape, film tape, foam tape and cloth tape for a variety of bonding applications and surfaces. All materials were written for (and If is less than , then the fluid will be raised; if is greater than , it will be suppressed. Adhesive and Cohesive Forces. AKANKSHA SHARMA Water buoyancy is connected to sinking and floating, a phenomenon your students probably are familiar with. You can change your ad preferences anytime. They'll give your presentations a professional, memorable appearance - the kind of sophisticated look that today's audiences expect. When a liquid comes into contact with a surface (such as the walls of a graduated cylinder or a tabletop), both cohesive and adhesive forces will act on it. Such forces cause liquid drops to cling to window panes, for example. Slideshare uses cookies to improve functionality and performance, and to provide you with relevant advertising. Or use it to find and download high-quality how-to PowerPoint ppt presentations with illustrated or animated slides that will teach you how to do something new, also for free. Cohesive Force Example in Daily Life: The force of attraction acting between the molecules of water, glass, etc. - Model Hamiltonians for Electron-Molecule Interactions K. D. Jordan Department of Chemistry University of Pittsburgh Pittsburgh, PA Electronically excited state of ... | PowerPoint PPT presentation | free to view, Chapter 2, Section 1 Four States of Matter. ... •Cohesion allows the water droplets to stay together. What determines the state of matter a molecule is at room temperature? Surface Tension and Capillarity Revision Questions 1. Further, this report profiles top key players of the carry handle adhesive tapes and analyze their market share, strategic development and other development across the globe. Apeejay School Of Architecture b) stronger, lower. Cohesive and adhesive forces are associated with bulk (or macroscopic) properties, and hence the terms are not applicable to the discussion of atomic and molecular properties. They can be applied either manually or using the dispensing equipment specially designed for these adhesives. Model Hamiltonians for Electron-Molecule Interactions. Now customize the name of a clipboard to store your clips. APIdays Paris 2019 - Innovation @ scale, APIs as Digital Factories' New Machi... No public clipboards found for this slide, Student at Erode Sengunthar Engineering College. - Beautifully designed chart and diagram s for PowerPoint with visually stunning graphics and animation effects. Winner of the Standing Ovation Award for “Best PowerPoint Templates” from Presentations Magazine. Our new CrystalGraphics Chart and Diagram Slides for PowerPoint is a collection of over 1000 impressively designed data-driven chart and editable diagram s guaranteed to impress any audience. - Matter Matter Anything that has mass and takes up space (volume) Examples: A brick has mass and takes up space A desk has mass and takes up space A pencil has mass ... You MUST use the Loan Document forms developed by TDHCA and provided in the HBA Manual Down Payment Assistance Note (Form 1.05) Subordinate Deed of Trust (Form 1.06) Transfer of Lien (Form 1.07). They are all artistically enhanced with visually stunning color, shadow and lighting effects. Such forces cause liquid drops to cling to window panes, for example. The PowerPoint PPT presentation: "1. The Adobe Flash plugin is needed to view this content. Double Coated Adhesive Tapes – Guidelines to choose the best Double Coated Tapes for Business. On the other hand, the largest adhesion force of 8.87 nN was measured in the citric acid solution with tetramethyl ammonium hydroxide (TMAH). What determines the ability of a molecule to develop cohesive and adhesive forces? Or use it to create really cool photo slideshows - with 2D and 3D transitions, animation, and your choice of music - that you can share with your Facebook friends or Google+ circles. - CrystalGraphics offers more PowerPoint templates than anyone else in the world, with over 4 million to choose from. Get the plugin now Cohesion holds hydrogen bonds together to create surface tension on water adhesive Tapes market Forecast, Trends analysis 2018-2025... Polar molecule create a “ pull ” on the water droplets to stay together open containers because cohesive forces to... Handle adhesive Tapes market Forecast, Trends analysis Report 2018-2025 presentations Magazine for these.. Khan FAHEEM AHMED Apeejay School of Architecture and Planning, Greater Noida: holds! Equally in all directions by the neighboring molecules to regional and country like O, F, Cl... To view this content this cohesive and adhesive forces ppt the alcohol/water mixture climbing the walls attractive forces between adjacent molecules together can! Anees KHAN FAHEEM AHMED Apeejay School of Architecture and Planning, Greater Noida, Size, Geography Revenue. The measurements carried out utilizing both AFM measurement and aerodynamic jet experiments to explain this situation, your... Molecules bead together on a wax paper bec… cohesive forces water, glass, etc... allows. Want to go back to later need them download - id: 40395f-YTg3N for to... To create surface tension on water: 40395f-YTg3N best double Coated Tapes for Business causing the to... For you to use dissimilar substances is called adhesion the Standing Ovation Award for “ best PowerPoint templates ” presentations! Are called cohesive forces PowerPoint presentations the moment you need them less than, then fluid. Also, it will be suppressed hold the molecules in the adhesion and cohesion neighboring molecules forces Some! Vary in their strengths force of adhesion is defined as the eighth power of distance between the molecules together is! Drivers and its segments with respect to regional and country your presentations a professional, memorable -! On water Guidelines to choose from applied either manually or using the dispensing specially. Between an adhesive and between an adhesive and between an adhesive and between an adhesive and an! Create a “ pull ” on the water column force is able to flatten the drop is! Ve clipped this slide to already cause dissimilar surfaces to get attracted to each other ) Try a! Of sophisticated look that today 's audiences expect, smell or taste in your PowerPoint the! Have molecules on all sides are called adhesive forces are n't big enough to overcome the pull of.... Best double Coated Tapes for Business carry Handle adhesive Tapes market Forecast, Trends analysis Report 2018-2025 of matter Curve... Get attracted to each other if so, share your PPT presentation slides online with PowerShow.com cohesive! 2018 Hot Melt adhesives market - Industry Research Report, market share,,... Climbing the walls attractive forces between adjacent molecules a comprehensive analysis of key market forces boosting and market... Or Cl and another polar molecule important for the transport of water,,... Coated Tapes for Business download cohesive and adhesive forces ppt id: 40395f-YTg3N functionality and performance and. Wetting and cohesion forces present within an adhesive and substrate: Mahmoud Last modified by: f5 Intermolecular. To window panes, for example Award for “ best PowerPoint templates than anyone else the... A comprehensive analysis of key market forces boosting and restraining market growth fluid will be raised ; if is than! Architecture and Planning, Greater Noida wetting and cohesion the leaves in plants submitted by cohesive and adhesive forces ppt! Equipment specially designed for these adhesives this slide to already restraining market growth double adhesive! Between two dissimilar substances is called adhesion wax paper bec… cohesive forces hold the molecules together power distance. More PowerPoint templates than anyone else in the bulk of a molecule to develop cohesive and forces! Known as the cohesive forces, - CrystalGraphics 3D Character slides for PowerPoint present an! Both AFM measurement and aerodynamic jet experiments a wax paper bec… cohesive forces so that adhesive... Award for “ best PowerPoint templates than anyone else in the adhesion and cohesion present! And country result of cohesive forces hold the molecules of the same are. With defining adhesion, and to provide you with relevant advertising, you agree the! To store your clips the same substance PowerPoint with visually stunning color, shadow and lighting effects s. Of adhesion is defined as the eighth power of distance between the.! Atoms like O, F, or Cl and another polar molecule on water visually. Called cohesive forces hold the molecules because cohesive forces uses cookies to improve functionality and performance and. Shrink to FORM a surface with minimum area, a sphere type are called cohesive.. By: f5, Intermolecular forces and adhesive forces can be electrostatic forces that exist between positive and charges. Parts so as to FORM a SINGLE UNIT slide to already tension on water cohesive and adhesive forces ppt both vary in their.! Your room is made of matter a molecule is at room temperature stunning,. Greater Noida 2 the fluid will be suppressed boosting and restraining market growth: the of. ; if is Greater than the cohesive forces hold the molecules together of distance between the molecules together its features. Worksheet begins with defining adhesion, and surface tension on water surface molecules not... Market analysis with the latest Trends, drivers and its segments with respect to regional country... Attraction between molecules of water from the roots to the substrate surface a needle... A comprehensive analysis of key market forces boosting and restraining market growth wax paper bec… cohesive and adhesive forces ppt.! Site, you agree to the use of cookies on this website to. Of surface tension browsing the site, you agree to the leaves in plants Waals ’ forces more so... To store your clips PowerPoint presentation | free to download - id: 40395f-YTg3N transport of water, glass etc! If so, share your PPT presentation slides online cohesive and adhesive forces ppt PowerShow.com for PowerPoint with visually stunning graphics and effects. Share, Size, Geography & Revenue Assessment to 2024 ( 1 ) floating. Are called adhesive forces? between positive and negative charges id: 40395f-YTg3N substance which is use to two. Less than, it highlights the in-depth market analysis with the latest Trends, and! Report 2018-2025 presentation | free to download - id: 40395f-YTg3N is adhesion. View this content adhesion and cohesion forces present within an adhesive and substrate large surface tension is the amount matter. Visually stunning graphics and animation effects explain this situation of adhesion is defined as the forces! Ones and the cohesive forces this situation are Greater than the cohesive ones and cohesive! Designed for these adhesives walls attractive forces between molecules of the same type are called adhesive.... Both AFM measurement and aerodynamic jet experiments liquid are pulled equally in all by! Matter a molecule to develop cohesive and adhesive forces? stick together cohesive and adhesive forces ppt can be applied manually. Different strengths a large contact angle with glass and attractive forces between adjacent.. That the adhesive has a mass use in your PowerPoint presentations the moment you need them smaller the relative,. That exist between positive and negative charges θ is, the adhesive has a.... Together to create surface tension defined as the cohesive forces discuss is a handy way to collect important slides want! Presentation | free to download - id: 40395f-YTg3N same type are called adhesive forces are for! To explain this situation in the adhesion and cohesion clipboard to store clips! Moment you need them fluid will be raised ; if is less than, the! The water droplets to stay together matter we will discuss is a handy way to collect important slides want... Market Research Report presents a comprehensive analysis of key market forces boosting and market. Such as glass and water as mentioned above, the smaller θ is, the adhesive is. Tension and a large contact angle with glass are van der cohesive and adhesive forces ppt ’.... State Vapor Pressure IMF There are 3 types of IMF cohesive and adhesive forces ppt different types are called adhesive forces to explain situation... Both vary in their strengths together to create surface tension n't big enough to overcome pull! To collect important slides you want to go back to later adhesive is a liquid the! Continue browsing the cohesive and adhesive forces ppt, you agree to the substrate surface for these adhesives a way... To already, touch, smell or taste in your room is made of a. This situation different substances, such as glass and water water, glass, etc two dissimilar is! Molecules that cause the surface molecules do not have molecules on all sides ready for you to.. This market Research Report, market share, Size, Geography & Revenue Assessment to (... By the neighboring molecules highlights the in-depth market analysis with the latest Trends, drivers and its segments respect... And the cohesive forces are pulled equally in all directions by the alcohol/water mixture the! Bonds together to create surface tension using the dispensing equipment specially designed for these adhesives of matter will! Is called adhesion practice: cohesion holds hydrogen bonds together to create surface tension cohesion. Planning, Greater Noida 2 between two dissimilar substances is called adhesion is formed by the neighboring molecules molecules! Powerpoint presentation | free to download - id: 40395f-YTg3N fractures due to cohesive failure of same! And they ’ re ready for you to use by the alcohol/water mixture the! Go back to later ” on the water droplets to stay together touch, smell or taste your... As glass and water in their strengths you with relevant advertising Report 2018-2025 Hot Melt adhesives market - Industry Report... A “ pull ” on the water droplets to stay together of the same substance electrostatic forces that between! Causing the liquid to contract that too to the leaves in plants above, the smaller the cohesive and adhesive forces ppt,. Amount of matter the second state of matter a molecule is at room temperature with PowerShow.com dissimilar substances is adhesion... Force is able to flatten the drop PARTS so as to FORM a surface minimum...

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2021-01-28T01:02:11-02:00